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Boiling |

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Hops are added at appropriate times during the boil, changing the sweet wort into what we now call bitter wort. Hops contain complex organic chemicals known as alpha acids that are extracted during the boil. These alpha acids impart a bitterness to the brew, necessary to offset the sweetness that will be left by non-fermentable sugars. Since they are not very soluble, the amount of bitterness extracted from the hops depends on the length of time that they are boiled. On the other hand, prolonged boiling will drive out other organic chemicals that impart hop flavors and aromas. For this reason, most recipes will call for hops to be added in multiple courses during the boil so that we get bitterness, hop flavors, and hop aromas in appropriate amounts.
Hops intended to impart bitterness are boiled the longest (60 to 90 minutes). This maximizes the amount of alpha acids that are extracted, but most of the hop flavor and aroma is lost. Hops intended to impart flavor are boiled for a shorter time (10 to 15 minutes). While there is far less extraction of alpha acids, there is also less loss of the substances that impart hop flavors. After boiling even for this short time, however, most of the substances that provide hop aromas will be lost. Hops intended to impart aroma are boiled the least (less than 5 minutes). In most cases, in fact, aroma hops are added at the very end of the boil so that they merely steep in the hot wort before it is cooled, and are not actually boiled at all. Little or no alpha acid is extracted. Aromatic oils and substances that provide hop aroma and flavor are the only items we get from these hops. Another method to use hops is to add them to the keg of beer after fermentation has occurred. Called dry hopping, this technique adds a dramatic amount of hop flavor and aroma to the finished beer. Dry hopping cannot be done in bottled beer.

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While there is a considerable difference among these forms in terms of their storage characteristics and
convenience in use, they can otherwise be considered as identical.
You can even mix the different forms of hops within the same batch.
As will be seen shortly, having intact hop petals after the boil is complete is useful in subsequent steps.
For this reason, it is a good idea for half of the hops used in a batch to be in either whole form or plug form.
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